I Spy.

The International Spy Museum in DC holds regular "SpyCasts" with cloak-and-dagger guests; recent podcasts feature Milt Bearden, a former CIA station chief; Jonna Hiestand Mendez, a former head of the CIA's Office of Technical Services (which develops gadgets, among other things); and Tony Mendez, who extracted six Americans from Iran with the help of the Canadian Embassy during the 1979 hostage crisis.